Multi-chiro-informative System Created by a Porphyrin-functionalized Chiral Molecular Assembly

We introduce multi-chiroptically active organic systems that exhibit circular dichroism, fluorescence and circularly polarized luminescence through chiral molecular orientation of a non-chiral porphyrin moiety. The spectra of these unique systems are distinctly sensitive to external conditions, including an enantiomeric factor. We introduce multi-chiroptically active organic systems that exhibit circular dichroism, fluorescence and circularly polarized luminescence through chiral molecular orientation of a non-chiral porphyrin moiety. The spectra of these unique systems are distinctly sensitive to the external conditions, including an enantiomeric factor.