The solution of the RISM equation for polar hard dumb-bells (PHD) within the mean spherical approximation is presented. The dielectric constant for a fluid of such molecules is found to be given by ε=1+3y. A charged tetrahedral RISM molecule is proposed as a simple model for water. The solution of the RISM equation for this molecule and the dielectric constant are also obtained.
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Morriss et al. (1981) studied this question.
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