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Reaction of ozone with three kinds of olefins in air was studied. H2O2, CH3OOH, and HOCH2OOH were collected and analyzed with HPLC with a fluorometric detector. Direct reaction of CH2OO with H2O was found to be the source of HOCH2OOH. CH3OOH was formed only from the olefins which have a methyl group. Detailed reaction mechanisms are discussed.
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Hatakeyama et al. (1993) studied this question.
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