The mass spectra of oligosaccharides such as glucose, sucrose, lactose and raffinose obtained by static secondary ion mass spectrometry operated at 10 −6 Torr are presented. Cationized molecular ions are observed in high intensity. Fragment ions are compared with daughter ions produced by collision induced dissociation of field desorbed cationized molecular ions.
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Kambara et al. (1981) studied this question.
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