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A new nonrigid PN-phosphine ligand, 1-[(diphenylphosphino)methyl]-4-(2-pyridyl)piperazine (L1), has been synthesized and its centrosymmetric binuclear silver(I) complex [Ag(μ-L1)(O3SCF3)]2, 1, and mononuclear iron(0) complex Fe(CO)3(L1)2, 2, have been structurally characterized by single-crystal X-ray analysis.
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Kuang et al. (1998) studied this question.
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