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Crystalline ethyl and propyl 1,2-orthoacetates of α-D-glucopyranose triacetate were prepared. Conclusions are drawn regarding the chemical properties and configurations of these compounds which are based on the conformation of the 1,2-cyclic carboxonium ion believed to be formed when the substances are treated with acetic acid.
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Lemieux et al. (1956) studied this question.
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