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Electron spin resonance analysis reveals fine and hyperfine structures of rare-earth monoclinic centers in yttrium orthoaluminate, clarifying local crystal-field interactions.
The ESR spectrum of Gd 3+ and Eu 2+ monoclinic centers, which substitute for yttrium ions in YAlO 3 crystals doped with europium and zirconium, has been investigated. Parameters of the fine structure of these centers are determined. The hyperfine-interaction parameters are determined for the centers with 151 Eu isotope, and the hyperfine structure of the centers with 153 Eu isotope is discussed.
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Vazhenin et al. (2017) studied this question.
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