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The new microporous metal−organic framework Cu[Ni(pdt)2] (pdt2− = pyrazine-2,3-dithiolate) is demonstrated to have an optical bandgap, p-type semiconductivity, and redox activity. The compound can be doped by using I2 as an oxidant, leading to an increase in conductivity by 4 orders of magnitude with retention of porosity.
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Kobayashi et al. (2010) studied this question.
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