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February 1, 2009Bulletin of the Chemical Society of Japan

Synthesis of Prenylarenes and Related (Multisubstituted Allyl)arenes from Aryl Halides and Homoallyl Alcohols via Palladium-Catalyzed Retro-Allylation

Masayuki Iwasaki Hideki Yorimitsu Koichiro Oshima

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Abstract

The reactions of aryl halides with 2,3,3-trimethyl-4-penten-2-ol in the presence of a palladium catalyst result in prenyl transfer from the alcohol to aryl halides via retro-allylation, yielding prenylarenes. Other multisubstituted allyl groups such as the 2,3-dimethyl-2-butenyl group are introduced to aromatic rings.

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Iwasaki et al. (2009) studied this question.

synapsesocial.com/papers/6a73178a57d56039052c14fd https://doi.org/10.1246/bcsj.82.249

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