Mechanical and thermal properties of SEBS‐g‐MA compatibilized halloysite nanotubes reinforced polyethylene terephthalate/polycarbonate/nanocomposites

In this study, the effect of maleic anhydride grafted styrene‐ethylene‐butylene‐styrene (SEBS ‐g‐ MA) content on mechanical, thermal, and morphological properties of polyethylene terephthalate/polycarbonate/halloysite nanotubes (PET/PC/HNTs) nanocomposites has been investigated. Nanocomposites of PET/PC (70 : 30) with 2 phr of HNTs were compounded using the counter rotating twin screw extruder. A series of formulations were prepared by adding 5–20 phr SEBS ‐g‐ MA to the composites. Incorporation of 5 phr SEBS ‐g‐ MA into the nanocomposites resulted in the highest tensile and flexural strength. Maximum improvement in the impact strength which is 245% was achieved at 10 phr SEBS ‐g‐ MA content. The elongation at break increased proportionately with the SEBS ‐g‐ MA content. However, the tensile and flexural moduli decreased with increasing SEBS ‐g‐ MA content. Scanning electron microscopy revealed a transition from a brittle fracture to ductile fracture morphology with increasing amount of SEBS ‐g‐ MA. Transmission electron microscopy showed that the addition of SEBS ‐g‐ MA into the nanocomposites promoted a better dispersion of HNTs in the matrix. A single glass transition temperature was observed from the differential scanning calorimetry test for compatibilized nanocomposites. Thermogravimetric analysis of PET/PC/HNTs nanocomposites showed high thermal stability at 15 phr SEBS ‐g‐ MA content. However, on further addition of SEBS ‐g‐ MA up to 20 phr, thermal stability of the nanocomposites decreased due to the excess amount of SEBS ‐g‐ MA.