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Mercury microelectrodes, fabricated by electrodeposition on an inlaid disk, adopt the shape of a sphere cap. This article derives the steady-state diffusion-limited voltammetric current at such electrodes and correlates the current with the radius, area, and volume of the sphere cap. Also predicted are the steady-state currents at an entire sphere emerging from an insulating plane.
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Alfred et al. (1996) studied this question.
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