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The yield and the rate of formation of nitriles X-CH=CH-CN and 3- and 4-substituted nitriles X-C 6 H 5 CN (X = CH 3 ; OR; SR; COOCH 3 ) were investigated in the reaction of vinyl and aryl bromides with CN (-) , under catalysis with Pd 0 and macrocyclic polyethers, and in the reaction with CuCN in dipolar aprotic solvents. Individual procedures were compared from the point of view of the possibility of a preparative utilization.
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Procházka et al. (1983) studied this question.
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