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9,10-Diphenylanthracene (DPA) permits the inclusion of guest molecules (hexafluorobenzene and 1,4-dioxane) by changing the arrangement of its two-dimensional layers and the size of the cavities formed by these layers in a solid state. In particular, the 1,4-dioxane guest molecules are trapped along the cavities by CH-π interactions with DPA. Crystal data for hexafluorobenzene inclusion complex in DPA, triclinic, space group , a = 6.118(2 Atwood , J. L. (Ed.), ( 1990 ). In Inclusion Phenomenon and Molecular Recognition , Plenum Press : New York .[Crossref] , [Google Scholar]), b = 7.571(2 Atwood , J. L. (Ed.), ( 1990 ). In Inclusion Phenomenon and Molecular Recognition , Plenum Press : New York .[Crossref] , [Google Scholar]), c = 12.982(4 Atwood , J. L. & Steed , J. W. (Eds.). ( 2004 ). Encyclopedia of Supramolecular Chemistry , Mercel Dekker : New York .[Crossref] , [Google Scholar]) Å, α = 78.366(4 Atwood , J. L. & Steed , J. W. (Eds.). ( 2004 ). Encyclopedia of Supramolecular Chemistry , Mercel Dekker : New York .[Crossref] , [Google Scholar])°, β = 85.001(5 Toda , F. & Bishop , R. , (Eds.). ( 2004 ). Perspectives in Supramolecular Chemistry , John Wiley & Sons : Chichester , UK , Vol. 8 . [Google Scholar])°, γ = 81.687(5 Toda , F. & Bishop , R. , (Eds.). ( 2004 ). Perspectives in Supramolecular Chemistry , John Wiley & Sons : Chichester , UK , Vol. 8 . [Google Scholar])°, U = 581.7(3 Lehn , J.-M. , Atwood , J. L. , Davies , J. E. D. , MacNicol , D. D. , & Vogtle , F. , Eds. ( 1996 ). Comprehensive Supramolecular Chemistry , Pergamon Press : Oxford , Vols. 1–11 . [Google Scholar]) Å3, Z = 2. Crystal data for 1,4-dioxane inclusion complex in DPA, triclinic, space group , a = 5.931(1 Atwood , J. L. , Davies , J. E. D. , & MacNicol , D. D. (Eds.). ( 1984 ). Inclusion Compounds , Academic Press : New York , Vols. 1–3 . [Google Scholar]), b = 7.625(1 Atwood , J. L. , Davies , J. E. D. , & MacNicol , D. D. (Eds.). ( 1984 ). Inclusion Compounds , Academic Press : New York , Vols. 1–3 . [Google Scholar]), c = 12.103(1 Atwood , J. L. , Davies , J. E. D. , & MacNicol , D. D. (Eds.). ( 1984 ). Inclusion Compounds , Academic Press : New York , Vols. 1–3 . [Google Scholar]) Å, α = 85.404(2 Atwood , J. L. (Ed.), ( 1990 ). In Inclusion Phenomenon and Molecular Recognition , Plenum Press : New York .[Crossref] , [Google Scholar])°, β = 76.300(2 Atwood , J. L. (Ed.), ( 1990 ). In Inclusion Phenomenon and Molecular Recognition , Plenum Press : New York .[Crossref] , [Google Scholar])°, γ = 82.909(2 Atwood , J. L. (Ed.), ( 1990 ). In Inclusion Phenomenon and Molecular Recognition , Plenum Press : New York .[Crossref] , [Google Scholar])°, U = 526.96(9 Ooyama , Y. & Yoshida , K. ( 2005 ). New J. Chem. , 29 , 1204 .[Crossref], [Web of Science ®] , [Google Scholar]) Å3, Z = 2.
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Imai et al. (2008) studied this question.
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