This randomized trial demonstrates a new method for synthesizing alkenylsilanes, indicating broader applications for alkenyl sulfonium salts.
The synthesis of alkenylsilanes from alkenyl sulfonium salts with silanes through a visible-light-induced radical coupling reaction has been developed. This protocol has expanded the applications of the alkenyl sulfonium salts, achieving the synthesis of alkenylsilanes under metal-free photocatalytic conditions and affording products with E-selectivity in moderate to good yields.
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Xiao et al. (2026) studied this question.
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