Increased stability of oxidation catalysts results from the self-assembly of the catalysts under near-turnover conditions from oxidatively resistant precursors. The described polyoxometalate epoxidation catalyst uses a green oxidant (H2O2), solvent, and separation conditions and is fast, selective, and safe. This self-assembling system is an important step towards truly green catalysis (see scheme).
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Craig L. Hill (2004) studied this question.
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