The ruthenium-hydride complexes, [RuHCl(PPh3)3] and [RuH2(PPh3)4] act as very active catalyst for transfer hydrogenation of ketones and imines by propan-2-ol. The ruthenium-dihydride complex, [RuH2(PPh3)4], could catalyze the transfer hydrogenation without base.
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Mizushima et al. (1997) studied this question.
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