A penny saved is a penny earned: The use of propylene carbonate as the solvent in iridium-catalyzed hydrogenations of nonfunctionalized olefins allows efficient catalyst recycling through the formation of two-phase mixtures with nonpolar solvents such as n-hexane. In the picture, the hydrogenated tetrahydronaphthalene derivative is extracted into the hydrocarbon phase.
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Bayardon et al. (2007) studied this question.
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