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A heterogeneous palladium catalyst, which is supported on a metal–organic framework, MIL-101, is highly efficient in water-mediated coupling reactions of chloroarenes. High yields are obtained in Suzuki–Miyaura cross-coupling and Ullmann homocoupling reactions of substituted aryl chlorides. Furthermore, the catalyst is easily recoverable and reusable (see picture; Cr blue, O red, C white).
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Yuan et al. (2010) studied this question.
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