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January 1, 1993Journal of the Chemical Society Chemical Communications

Cyclopropanes via nucleophilic attack at the central carbon of (π-allyl)palladium complexes

Andreas Wilde Andreas R. Otte H. M. R. Hoffmann

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Abstract

A variety of carboanions (pKa of protonated carbanion 20) combine with (π-allyl)palladium complexes in the presence of N, N, N′, N′, tetramethylethylenediamine (TMEDA)via a new reaction mode, giving functionalized cyclopropanes.

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Wilde et al. (1993) studied this question.

synapsesocial.com/papers/6a7e0d1d1693de70af99ba2a https://doi.org/10.1039/c39930000615

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