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Large-scale lithium-ion energy storage systems (ESSs) are indispensable for renewable energy integration and grid support, yet ensuring long-term reliability under field conditions remains challenging. This study investigates degradation trends in a 50 MW-class ESS deployed on Jeju Island, South Korea, focusing on two indicators: direct current internal resistance (DCIR) and state-of-health (SOH). Annual round-trip (capacity) and hybrid pulse power characterization (HPPC) tests conducted from 2023 to 2025 quantified capacity fade and resistance growth. A polynomial-regression-based temperature compensation was applied—compensating DCIR to 23 °C and SOH to 30 °C—which reduced environmental scatter and clarified year-to-year degradation trends. Beyond mean shifts, intra-bank variability increased over time, indicating rising internal imbalance. A focused case study (Bank 03-01) revealed concurrent SOH decline and DCIR escalation localized near specific racks; spatial maps linked this hotspot to heating, ventilation, and air conditioning (HVAC)-driven airflow asymmetry and episodic fan operation. These findings underscore the importance of combining temperature compensation, variability-based diagnostics, and spatial visualization in field ESS monitoring. The proposed methodology provides practical insights for the early detection of abnormal degradation and supports lifecycle management of utility-scale ESSs under real-world conditions.
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Mun et al. (2025) studied this question.
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