A quinoline‐based ligand effectively promotes the palladium‐catalyzed borylation of C(sp 3 )H bonds. Primary β‐C(sp 3 )H bonds in carboxylic acid derivatives as well as secondary C(sp 3 )H bonds in a variety of carbocyclic rings, including cyclopropanes, cyclobutanes, cyclopentanes, cyclohexanes, and cycloheptanes, can thus be borylated. This directed borylation method complements existing iridium(I)‐ and rhodium(I)‐catalyzed CH borylation reactions in terms of scope and operational conditions.
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He et al. (2015) studied this question.
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