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August 16, 2026BatteriesOpen Access

Lipoic Acid-Derived Interphase for Stable Lithium Metal Anodes in High-Performance Lithium Metal Batteries

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Authors

LZLiyuan ZhangCentral University of Finance and EconomicsCLChen LiangCentral University of Finance and EconomicsJXJiarong XuGuangzhou Design Institute

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Overview

Experimental study demonstrates enhanced cycling stability in lithium metal batteries via a lipoic acid-derived interphase, indicating a scalable pathway for high-energy storage.

Key Points

  • To develop a stable artificial solid electrolyte interphase on lithium metal anodes using a rapid lipoic acid pretreatment to mitigate dendrite formation and interfacial degradation.
  • Synthesized an artificial solid electrolyte interphase composed of COO-Li species and sulfur-containing compounds via the chemical reaction of lipoic acid with lithium metal.
  • Tested electrochemical cycling in symmetric cells at 5 mA cm⁻² with a 5 mAh cm⁻² capacity and evaluated practical scalability in lithium-sulfur and lithium-iron phosphate pouch cells.
  • Lipoic acid-modified lithium symmetric cells sustained over 1500 hours of continuous cycling stability at 5 mA cm⁻² and 5 mAh cm⁻².
  • Full-cell configurations, including lithium-sulfur and lithium-iron phosphate pouch cells, demonstrated substantially enhanced cycling performance compared to cells using bare lithium anodes.

Cite This Study

Zhang et al. (2026) studied this question.

synapsesocial.com/papers/6a8179cbf2fb91fc834ad239https://doi.org/10.3390/batteries12080307
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