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Enantioselective radical-mediated reduction of α-methoxymethyl-α-iododihydrocoumarin 1 using tributyltin hydride is realized in up to 62% enantiomeric excess (e.e.)(88% chemical yield) by combination of chiral diamine 2 and magnesium iodide.
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Murakata et al. (1995) studied this question.
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