Structure and Properties of Biopolymeric Fibrous Materials Based on Polyhydroxybutyrate–Metalloporphyrin Complexes

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Ultrathin fibrous materials based on natural bacterial polymer polyhydroxybutyrate (PHB) were prepared by the electrospinning method. Using scanning electron and optical microscopy techniques the macrophysical characteristics of the fibrous layer were determined and classified. The physicomechanical characteristics of the resultant materials and their changes caused by ozonation were determined as well. Structure formation in the ultrathin polyhydroxybutyrate fibers containing low antibacterial concentrations was studied. The effect of low concentrations of zinc tetraphenylporphyrin and iron(III) chloroteteraphenylporphyrin complexes on the structure of polyhydroxybutyrate-based ultrathin fibers was elucidated. Techniques used in the study were X-ray diffraction analysis, ESR spin probe method, differential scanning calorimetry, and optical and electron scanning microscopy. It was shown that addition of the metal porphyrin complexes caused changes in the degree of crystallinity and in the crystallite size of the PHB fibers, while the proportion of dense domains in the amorphous phase of the polymer fiber increased.