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Square wave gratings with periodicities as small as 1.4 μm have been etched into fused quartz by reactive sputter etching in CF4 and CHF3. Grooves with a perfectly rectangular cross section have been etched with a depth of up to 3 μm. The etching is probably due to highly reactive species produced directly on the substrate surface by an ion-induced dissociation process.
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Lehmann et al. (1978) studied this question.
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