A tetrapodal calix-4-resorcinarenethiol has been immobilised in a gold–thiol monolayer; the layer shows strong selectivity for some adsorbates from dilute solutions and the non-adsorption from bulk solutions by related calix-4-resorcinarenes may be accounted for on the basis of an X-ray crystal structure.
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Adams et al. (1994) studied this question.
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