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The 'one pot' reaction between K[N(SiMe(3))(2)], InI and the beta-diimine ligand precursor [H(NDippCMe)(2)CH](Dipp = C(6)H(3)Pr(i)(2)-2,6) gave [In[(NDippCMe)(2)CH]], the first example of a two-coordinate, neutral, In(i) singlet 'carbene analogue'.
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Hill et al. (2004) studied this question.
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