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A crowning achievement: Appropriately sized crown ethers can stabilize or enable InI compounds to be generated without decomposition or disproportionation (see scheme). The resulting coordination compounds include the only example of a donor group complexed to a monomeric, univalent Group 13 center and the first example of a homoleptic Group 13–Group 13 donor–acceptor complex.
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Andrews et al. (2005) studied this question.
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