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The deposition of one monolayer of Sb followed by annealing of about 300 ^∘{}C gives nearly the flat-band condition for both n- and p-type InP(110). Schottky barriers were formed on these surfaces by using nonreactive metals, Au and Ag, and the surface-Fermi-level positions measured by photoemission spectroscopy converge at about 0.52 eV above the valence-band maximum (VBM) for both n- and p-type InP. A defect model using a donor level due to phosphorus deficiency at 0.55 eV (±{}0.05 eV) above the VBM is proposed as a most probable candidate responsible for this Schottky-barrier formation. However, it is also noted that the Sb interlayer could shift the metal-induced gap state's pinning position.
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Yamada et al. (1992) studied this question.
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