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The alloying behaviour of the Hg-Mg system is studied in terms of pseudopotentials and perturbation theory. The type of ordering in HgMg and Hg 2 Mg is explained, and the calculated dependence of energy on concentration of these phases is consistent with the observed phase diagram. Their narrow range of homogeneity is associated with their large ordering energies.
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J E Inglesfield (1969) studied this question.
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