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November 11, 1966Physical Review

Antiferromagnetism in Chromium Alloys. I. Neutron Diffraction

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Authors

WKW. C. KoehlerOak Ridge Associated UniversitiesRMR. M. MoonOak Ridge National LaboratoryATA.L. TregoOak Ridge National Laboratory

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Implication

Diffraction study demonstrates electron-concentration-driven magnetic transitions in chromium alloys, highlighting Fermi surface nesting mechanisms.

Key Points

  • Investigate how dilute additions of transition metals alter the antiferromagnetic properties and magnetic structure of chromium.
  • Evaluated magnetic properties of chromium alloys containing small amounts of V, Mn, Nb, Mo, Tc, Ru, Rh, Ta, W, or Re.
  • Conducted powder and single-crystal neutron-diffraction measurements to determine magnetic moments, wave vectors, and transition temperatures.
  • Solutes increasing the electron-to-atom ratio (Mn, Tc, Ru, Rh, Re) elevated the Néel temperature up to ~700°K and magnetic moment to ~0.75 μB (compared to 311°K and 0.40 μB in pure Cr), shifting the wave vector to 2π/a at ~1% concentration.
  • Elements decreasing the ratio (V, Nb, Ta) or maintaining it (Mo, W) suppressed Néel temperatures, magnetic moments, and wave vectors, with Ta showing the strongest suppression.
  • All examined dopants reduced the transverse-to-longitudinal magnetic transition temperature, with ordered moment variations matching the BCS energy-gap function.

Cite This Study

Koehler et al. (1966) studied this question.

synapsesocial.com/papers/6a8441bfa47fb2e1cdb29f11https://doi.org/10.1103/physrev.151.405
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Also Consider

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  1. 1A neutron-diffraction study of very pure chromium1961 · 128 citations
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  3. 3Fermi Surfaces of Cr, Mo, and W by the Augmented-Plane-Wave Method1965 · 179 citations
  4. 4Neutron Diffraction Studies of Various Transition Elements1953 · 276 citations
  5. 5Magnetic Structures of Field-Cooled and Stress-Cooled Chromium1966 · 60 citations