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August 1, 1961Acta Crystallographica

A neutron-diffraction study of very pure chromium

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Authors

GBG. E. BaconCarleton College

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Overview

Neutron diffraction study demonstrates grain-dependent antiferromagnetism in ultra-pure chromium, highlighting how microstructure and alloying alter transition temperatures.

Key Points

  • To investigate the antiferromagnetic ordering, atomic magnetic moment, and transition temperatures in single-crystal and polycrystalline samples of ultra-pure chromium.
  • Examined high-purity single-crystal and polycrystalline chromium samples containing 0.01% oxygen, 0.001% nitrogen, and 0.0002% metallic impurities by weight using neutron diffraction.
  • Evaluated magnetic structure across varying grain sizes and measured changes in transition behavior following the addition of 0.5% iron and 0.16% nickel.
  • Pure chromium lost the majority of its antiferromagnetic ordering at 40 °C, though residual order persisted in polycrystalline samples and increased as grain size decreased.
  • The magnetic moment localized on the chromium atom well below the Néel temperature was measured at approximately 0.45 μB across all sample types.
  • Doping the chromium with 0.5% iron and 0.16% nickel lowered the Néel temperature from 40 °C to 26 °C.

Cite This Study

G. E. Bacon (1961) studied this question.

synapsesocial.com/papers/6a8441c0a47fb2e1cdb29f18https://doi.org/10.1107/s0365110x61002412
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