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The photoionisation spectrum of atomic phosphorus prepared by successive abstraction reactions involving H atoms and PH 3 , is presented from its ionisation threshold to 765 A. Prominent autoionisation structure is observed between the fine-structure limits 3 P 2 - 3 P 0 near the ionisation threshold. In addition, a window resonance series is seen, involving inner s-shell excitation to . . .( 5 S)np 4 P states. Some systematic behaviour of resonance profiles and quantum defects in a series of atoms is discussed.
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Berkowitz et al. (1987) studied this question.
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