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A mathematical model for the calculation of thermodynamic properties of solids is described. The mathematical model, based on statistical thermodynamics, is designed to assess the impact of atom vibration, the electron excitation, and the effect of binding energy between atoms in a crystal. To calculate the cone guration integral, perturbation theory was used with the van der Waals model as the perturbation. The temperature-variable coefe cients were introduced into the model. Finally, the model was compared with experimental data, proving a good match.
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Avsec et al. (2002) studied this question.
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