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The crystal structure of [RuO2(bipy){IO3(OH)3}]·1.5H2O 1 is reported: with NaIO4 or NBun4IO4 as cooxidant it is an efficient catalyst for alkene epoxidations under mild conditions; it also oxidises primary alcohols to aldehydes and secondary alcohols to ketones.
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Bailey et al. (1994) studied this question.
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