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A novel [Pt 1 Ag 37 (SAdm) 21 (Dppp) 3 Cl 6 ] 2+ nanocluster is reported, and the reaction with PPh 3 triggers an intercluster transformation into [Pt 1 Ag 28 (SAdm) 18 (PPh 3 ) 4 ] 2+ . Using chiral Bdpp, the enantiomeric Pt 1 Ag 37 (SAdm) 21 ( R / S -Bdpp) 3 Cl 6 can be prepared.
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Zhen et al. (2022) studied this question.
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