A catalytic protocol for the unprecedented enantioselective monofluoromethylation of in situ generated prochiral imines using 1-fluorobis(phenylsulfonyl)methane (FBSM, 1 ) in the presence of a chiral PTC based on the Mannich-type reaction followed by reductive desulfonylation has been developed.
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Mizuta et al. (2007) studied this question.
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