A novel solvent system consisting of CuCl/aniline/n-methyl pyrrolidone was evaluated for the reactive absorption of ethylene. Equilibrium olefin loadings significantly exceeded physical solubility values. The equilibrium ethylene−ethane selectivity was a strong function of the gas phase total pressure. Kinetic behavior was accurately described by an instantaneous reversible mechanism. The solvent exhibited acceptable chemical stability during the experimental tests.
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Reine et al. (2005) studied this question.
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