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August 22, 2026Advanced Energy Materials

Entropy‐Mediated Nonporous Polymer Separator Unlocks Ultra‐Wide Temperature Range (−70°C to 150°C) Lithium Metal Batteries

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Authors

YWYongqi WangInner Mongolia UniversityYHYaodong HuoGuangdong University of Technology宋宋纯坤Inner Mongolia University

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Implication

Experimental study demonstrates stable lithium metal battery operation from −70°C to 150°C using a high-entropy polymer separator, highlighting enhanced thermal safety and stability.

Key Points

  • To develop a thermally robust battery separator capable of supporting lithium metal batteries across an ultra-wide temperature range from extreme cold to severe heat.
  • Synthesized a nonporous high-entropy separator (HES) using a high-entropy polymer architecture to improve thermal stability, ion transport, and electrolyte wettability.
  • Evaluated interfacial stability and electrochemical performance in Li||Li symmetric cells and Li||V2O5 full batteries across temperatures from −70°C to 150°C.
  • Li||Li symmetric cells demonstrated extended cycling life of 2,200 hours at −70°C, 6,548 hours at 25°C, and 700 hours at 150°C.
  • The separator facilitated inorganic- and boron-rich solid and cathode electrolyte interphases that suppressed lithium dendrite growth and parasitic reactions, enabling full Li||V2O5 battery operation from −70°C to 150°C.

Cite This Study

Wang et al. (2026) studied this question.

synapsesocial.com/papers/6a895f74ca7ade938187e24fhttps://doi.org/10.1002/aenm.71480
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