Self‐Assembly of Bidentate Ligands for Combinatorial Homogeneous Catalysis: Methanol‐Stable Platforms Analogous to the Adenine–Thymine Base Pair

Complementary partners: A combinatorial library of self-assembled ligand systems has been designed by analogy to the A–T base pair. When these ligand systems are applied in the rhodium-catalyzed hydroformylation of 1-octene (see scheme), high regioselectivities (rs) are obtained, even in the protic solvent methanol.