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Linear correlations of transition metal NMR chemical shifts with the logarithm of overall stability constants for six different series of complexes of Co(III), Rh(III), Rh(I) and Pt(II) have been found. Each case is presented and discussed. The relation is interpreted with a simplified version of Ramsey' s equation for the chemical shift. A derivation of a relation of the type δ = m – k logK using ligand field theory is proposed.
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Lars Öhrström (1996) studied this question.
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