Mo takes the tube: A saddle-distorted MoV–porphyrin complex forms a tubular assembly through intermolecular π–π interactions, which has an internal diameter of 1 nm (see picture). Within such tubes, tetranuclear MoVI–oxo clusters could be size-selectively included through intermolecular hydrogen-bonding interactions.
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Harada et al. (2004) studied this question.
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