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Conductivities of solutions of KCl, NaCl and LiCl in glycerol at 25°C have been measured for concentrations in the range 0.0005 to 0.5 mol dm−3, and values of molar conductivity at infinite dilution obtained by extrapolation. Using previously measured transference numbers for KCl dissolved in glycerol, values of ionic molar conductivities at infinite dilution have been deducted for K+, Na+, Li+ and Cl− ions. Values of ionic Walden products are calculated and compared with those in aqueous and other alcoholic solutions, the values for glycerol being the largest so far measured.
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Blanco et al. (1989) studied this question.
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