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The Bohr-Sommerfeld quantisation condition has a meaningful extension to classically chaotic systems whose periodic (unstable) orbits are isolated. It provides a semiclassical Euler factorisation for the functional determinant of the quantal Hamiltonian, in contrast to the Hadamard infinite product over the eigenvalues by which the exact determinant is defined.
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A. Voros (1988) studied this question.
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