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August 24, 2026Materials and StructuresOpen Access

Adhesion between geopolymer matrix and vegetable fibers: effect of matrix composition and fiber treatment

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Authors

HSHenrique A. SantanaPLPaulo Roberto Lopes LimaCDCléber Marcos Ribeiro Dias

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Overview

Experimental study demonstrates that matrix alkalinity and chemical treatments govern sisal fiber degradation and interfacial adhesion in geopolymer composites, highlighting the need for...

Key Points

  • To evaluate the interfacial adhesion, chemical degradation, and mechanical performance of natural and treated sisal fibers embedded in sustainable geopolymer matrices made from fiber cement waste and metakaolin.
  • Exposed natural, hornified, and sodium hydroxide–treated sisal fibers for 28 days to geopolymer matrices formulated with varying free alkali contents.
  • Assessed fiber-matrix durability and bonding via thermogravimetric analysis, scanning electron microscopy, tensile tests, and single-fiber pull-out testing.
  • Thermal stability declined across all exposed fibers, with cellulose decomposition peaks shifting downward by up to −63 °C in highly aggressive, high-alkali matrices.
  • Hornified fibers suffered severe alkaline hydrolysis and lost mechanical integrity, whereas sodium hydroxide–treated fibers retained superior tensile strength in lower free alkali environments.
  • Interfacial pull-out tests revealed premature fiber rupture in high-alkalinity matrices, compared to gradual pull-out behavior in less aggressive formulations.

Cite This Study

Santana et al. (2026) studied this question.

synapsesocial.com/papers/6a8c0086bca056c88e6df3f6https://doi.org/10.1617/s11527-026-03229-8
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