Answers are grounded in this paper and cite their sources.
A new calorimeter, suitable for the measurement of heats of mixing as small as 0·1 J resulting from the mixing of not more than 1cm3 of each component in the absence of any vapour phase and over a wide range of temperatures, is described. It has been used to measure heats of mixing for the pairs of liquids carbon tetrachloride + chloroform, carbon tetrachloride + cyclohexane, and benzene + solutions of biphenyl in benzene. The results are examined in the light of current theories of solutions.
No takes yet. Share an insight, caveat, or question.
Adcock et al. (1954) studied this question.
Synapse has enriched 10 related papers. Consider them for comparative context: