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June 16, 1995Angewandte Chemie International Edition in English

Phosphorane Iminato Complexes of Manganese and Cobalt with Heterocubane Structure

Hans‐Joachim Mai Rolf Meyer zu Köcker Sigrid Wočadlo Werner Massa Kurt Dehnicke

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Abstract

Mn4N4 and Co4N4 cubes with almost square faces are found in the title compounds 1 and 2. They were obtained by the melt reaction of the anhydrous dihalides MnI2 and CoCl2, and Me3SiNPEt3. Complexes 1 and 2 are the first phosphorane iminato complexes of manganese(II) and cobalt(II) with heterocubane structure. equation image

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Cite This Study

Mai et al. (1995) studied this question.

synapsesocial.com/papers/6a9034065b9c0fc32f8a4029 https://doi.org/10.1002/anie.199512351

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Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context:

1Darstellungen und Strukturen viergliedriger Metall-Stickstoff-RingeOriginal Research · 1988 · 21 citations
2Novel imido- and phosphorane-imido-nickel(II) complexes. Crystal and molecular structure of (.mu.3-NH)(.mu.3-NPMe3)(NiClPMe3)3Original Research · 1991 · 29 citations
3Supramolecular chemistry of manganese complex [Mn(CO)3(.mu.3-OH)]4: assembly of a cubic hydrogen-bonded diamondoid network with 1,2-diaminoethaneOriginal Research · 1992 · 125 citations
4Supramolecular properties of [Mn(CO)3(μ3-OH)]4, a neutral organometallic molecule that is capable of binding a variety of small and large guest moleculesOriginal Research · 1992 · 22 citations
5Formation of Interwoven 2‐D Networks by the Spontaneous Strict Self‐Assembly of [{M(CO)3(μ3‐OH)}4] (M Mn, Re) and Complementary Angular Spacer MoleculesOriginal Research · 1993 · 80 citations

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