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Cycloaddition of the nitrone, derived from tetradecanal, to 2-aminobut-3-en-1-ol provides a practical asymmetric synthesis of both (2R,4R,5S)-tetrahydropseudodistomin and all the stereoisomers of racemic tetrahydropseudodistomin.
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Naito et al. (1994) studied this question.
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