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Alkenes, alcohols, a sulfide, a sulfoxide and diphenylacetylene can be hetero-cooxygenated with PPh3 catalysed by a dicobalt complex: [Co2(µ-OH)L]{H3L = 2,6-bis[(2-hydroxyphenyl)iminomethyl]-4-methylphenol}, to produce a single oxidation product for each substrate.
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Hwang et al. (1992) studied this question.
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