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The synthetic method for the stepwise Ru3 unit elongation of pyrazine-bridged linear oligomer of trinuclear ruthenium complex with the Ru3(μ3-O)(μ-CH3COO)6 core has been developed, using a newly designed [Ru3(μ3-O)(μ-CH3COO)6(py)(CO)(H2O)] (py = pyridine) with labile and photoactive sites.
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Kido et al. (1996) studied this question.
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